| Date | Home | Away | Result |
|---|---|---|---|
| 01/09/23 19:30 | Borussia Dortmund | 1. FC Heidenheim 1846 | 2-2 |
| 02/09/23 14:30 | Bayer 04 Leverkusen | SV Darmstadt 98 | 5-1 |
| 02/09/23 14:30 | 1899 Hoffenheim | VfL Wolfsburg | 3-1 |
| 02/09/23 14:30 | Werder Bremen | FSV Mainz 05 | 4-0 |
| 02/09/23 14:30 | FC Augsburg | VfL Bochum | 2-2 |
| 02/09/23 14:30 | VfB Stuttgart | SC Freiburg | 5-0 |
| 02/09/23 17:30 | Bor. Mönchengladbach | FC Bayern Munich | 1-2 |
| 03/09/23 14:30 | Eintracht Frankfurt | 1. FC Köln | 1-1 |
| 03/09/23 16:30 | 1. FC Union Berlin | RB Leipzig | 0-3 |