| Date | Home | Away | Result |
|---|---|---|---|
| 03/02/23 19:30 | FC Augsburg | Bayer 04 Leverkusen | 1-0 |
| 04/02/23 14:30 | Borussia Dortmund | SC Freiburg | 5-1 |
| 04/02/23 14:30 | 1. FC Union Berlin | FSV Mainz 05 | 2-1 |
| 04/02/23 14:30 | 1. FC Köln | RB Leipzig | 0-0 |
| 04/02/23 14:30 | VfL Bochum | 1899 Hoffenheim | 5-2 |
| 04/02/23 14:30 | Eintracht Frankfurt | Hertha BSC | 3-0 |
| 04/02/23 17:30 | Bor. Mönchengladbach | FC Schalke 04 | 0-0 |
| 05/02/23 14:30 | VfB Stuttgart | Werder Bremen | 0-2 |
| 05/02/23 16:30 | VfL Wolfsburg | FC Bayern Munich | 2-4 |