| Date | Home | Away | Result |
|---|---|---|---|
| 03/10/23 18:00 | AD Alcorcon | Albacete Balompie | 1-2 |
| 03/10/23 18:00 | UD Levante | FC Villarreal B | 1-1 |
| 03/10/23 20:30 | CD Teneriffa | Racing Santander | 2-0 |
| 04/10/23 18:00 | Eldense | Real Valladolid | 0-1 |
| 04/10/23 18:00 | Real Oviedo | SD Huesca | 1-0 |
| 04/10/23 20:30 | Sporting Gijon | FC Elche | 2-0 |
| 04/10/23 20:30 | Burgos CF | CD Leganes | 1-0 |
| 05/10/23 18:00 | Andorra CF | Real Saragossa | 0-1 |
| 05/10/23 18:00 | CD Mirandes | SD Eibar | 1-3 |
| 05/10/23 20:30 | Racing de Ferrol | SD Amorebieta | 1-0 |
| 05/10/23 20:30 | FC Cartagena | Espanyol Barcelona | 0-2 |