| Date | Home | Away | Result |
|---|---|---|---|
| 29/09/23 20:00 | CD Leganes | Racing Santander | 2-1 |
| 30/09/23 15:15 | SD Eibar | CD Teneriffa | 3-0 |
| 30/09/23 17:30 | FC Elche | UD Levante | 0-0 |
| 30/09/23 20:00 | Albacete Balompie | Andorra CF | 3-1 |
| 30/09/23 20:00 | FC Villarreal B | AD Alcorcon | 2-2 |
| 01/10/23 13:00 | Eldense | Real Oviedo | 1-3 |
| 01/10/23 17:30 | SD Amorebieta | FC Cartagena | 0-0 |
| 01/10/23 17:30 | Real Valladolid | Burgos CF | 3-0 |
| 01/10/23 17:30 | Real Saragossa | CD Mirandes | 0-1 |
| 01/10/23 20:00 | SD Huesca | Sporting Gijon | 0-1 |
| 02/10/23 20:00 | Espanyol Barcelona | Racing de Ferrol | 3-0 |