| Date | Home | Away | Result |
|---|---|---|---|
| 08/09/23 20:00 | UD Levante | Espanyol Barcelona | 1-4 |
| 09/09/23 15:15 | Burgos CF | SD Eibar | 1-0 |
| 09/09/23 17:30 | Real Oviedo | Sporting Gijon | 0-0 |
| 09/09/23 20:00 | CD Teneriffa | Albacete Balompie | 2-0 |
| 09/09/23 20:00 | CD Leganes | SD Huesca | 2-0 |
| 10/09/23 15:15 | Racing Santander | SD Amorebieta | 1-0 |
| 10/09/23 15:15 | Racing de Ferrol | FC Villarreal B | 2-2 |
| 10/09/23 17:30 | CD Mirandes | Andorra CF | 4-3 |
| 10/09/23 17:30 | FC Cartagena | Real Saragossa | 1-3 |
| 10/09/23 20:00 | Real Valladolid | FC Elche | 1-1 |
| 11/09/23 20:00 | Eldense | AD Alcorcon | 2-2 |