| Date | Home | Away | Result |
|---|---|---|---|
| 03/11/23 20:00 | Espanyol Barcelona | SD Eibar | 2-2 |
| 04/11/23 15:15 | FC Villarreal B | Sporting Gijon | 0-3 |
| 04/11/23 17:30 | UD Levante | CD Mirandes | 2-2 |
| 04/11/23 17:30 | Real Valladolid | CD Teneriffa | 2-0 |
| 04/11/23 20:00 | Albacete Balompie | FC Elche | 1-1 |
| 05/11/23 13:00 | Racing de Ferrol | Andorra CF | 1-0 |
| 05/11/23 15:15 | SD Amorebieta | SD Huesca | 0-1 |
| 05/11/23 17:30 | FC Cartagena | CD Leganes | 0-3 |
| 05/11/23 17:30 | AD Alcorcon | Racing Santander | 3-1 |
| 05/11/23 20:00 | Eldense | Burgos CF | 2-0 |
| 06/11/23 20:00 | Real Saragossa | Real Oviedo | 0-0 |