Schedule
| Competition | Date | Dead line | Home | Away | Group | Result | Points rule |
|---|---|---|---|---|---|---|---|
| CL | 01/10/13 17:00 | 01/10/13 17:00 | Zenit St. Petersburg | FK Austria Wien | Group G | 0-0 | 4 - 8 points |
| CL | 01/10/13 19:45 | 01/10/13 19:45 | Steaua Bukarest | Chelsea FC | Group E | 0-4 | 4 - 8 points |
| CL | 01/10/13 19:45 | 01/10/13 19:45 | Arsenal FC | SSC Napoli | Group F | 2-0 | 4 - 8 points |
| CL | 01/10/13 19:45 | 01/10/13 19:45 | FC Porto | Atletico Madrid | Group G | 1-2 | 4 - 8 points |
| CL | 01/10/13 19:45 | 01/10/13 19:45 | Borussia Dortmund | Olympique Marseille | Group F | 3-0 | 4 - 8 points |
| CL | 01/10/13 19:45 | 01/10/13 19:45 | Ajax Amsterdam | AC Milan | Group H | 1-1 | 4 - 8 points |
| CL | 01/10/13 19:45 | 01/10/13 19:45 | Celtic Glasgow | FC Barcelona | Group H | 0-1 | 4 - 8 points |
| CL | 01/10/13 19:45 | 01/10/13 19:45 | FC Basel | FC Schalke 04 | Group E | 0-1 | 4 - 8 points |
| CL | 02/10/13 17:00 | 02/10/13 17:00 | CSKA Moscow | Viktoria Plzen | Group D | 3-2 | 4 - 8 points |
| CL | 02/10/13 19:45 | 02/10/13 19:45 | Juventus Turin | Galatasaray Istanbul | Group B | 2-2 | 4 - 8 points |
| CL | 02/10/13 19:45 | 02/10/13 19:45 | Manchester City | FC Bayern Munich | Group D | 1-3 | 4 - 8 points |
| CL | 02/10/13 19:45 | 02/10/13 19:45 | RSC Anderlecht | Olympiakos Piräus | Group C | 0-3 | 4 - 8 points |
| CL | 02/10/13 19:45 | 02/10/13 19:45 | Bayer 04 Leverkusen | Real Sociedad | Group A | 2-1 | 4 - 8 points |
| CL | 02/10/13 19:45 | 02/10/13 19:45 | Real Madrid | FC Copenhagen | Group B | 4-0 | 4 - 8 points |
| CL | 02/10/13 19:45 | 02/10/13 19:45 | Paris St. Germain | Benfica Lisbon | Group C | 3-0 | 4 - 8 points |
| CL | 02/10/13 19:45 | 02/10/13 19:45 | Schachtjor Donezk | Manchester United | Group A | 1-1 | 4 - 8 points |