| Date | Home | Away | Result |
|---|---|---|---|
| 31/01/23 17:00 | SC Paderborn 07 | VfB Stuttgart | 1-2 |
| 31/01/23 19:45 | 1. FC Union Berlin | VfL Wolfsburg | 2-1 |
| 01/02/23 17:00 | RB Leipzig | 1899 Hoffenheim | 3-1 |
| 01/02/23 19:45 | FSV Mainz 05 | FC Bayern Munich | 0-4 |
| 07/02/23 17:00 | SV Sandhausen | SC Freiburg | 0-2 |
| 07/02/23 19:45 | Eintracht Frankfurt | SV Darmstadt 98 | 4-2 |
| 08/02/23 17:00 | 1. FC Nürnberg | Fortuna Düsseldorf | 6-4a.PSO |
| 08/02/23 19:45 | VfL Bochum | Borussia Dortmund | 1-2 |