| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 29/08/25 18:30 | 29/08/25 18:30 | FC Elche | UD Levante | --- | 2 - 4 points |
| 29/08/25 20:30 | 29/08/25 20:30 | FC Valencia | FC Getafe | --- | 2 - 4 points |
| 30/08/25 16:00 | 30/08/25 16:00 | Deportivo Alaves | Atletico Madrid | --- | 2 - 4 points |
| 30/08/25 18:00 | 30/08/25 18:00 | Real Oviedo | Real Sociedad | --- | 2 - 4 points |
| 30/08/25 18:30 | 30/08/25 18:30 | FC Girona | FC Sevilla | --- | 2 - 4 points |
| 30/08/25 20:30 | 30/08/25 20:30 | Real Madrid | RCD Mallorca | --- | 2 - 4 points |
| 31/08/25 16:00 | 31/08/25 16:00 | Celta Vigo | FC Villarreal | --- | 2 - 4 points |
| 31/08/25 18:00 | 31/08/25 18:00 | Real Betis Sevilla | Athletic Bilbao | --- | 2 - 4 points |
| 31/08/25 18:30 | 31/08/25 18:30 | Espanyol Barcelona | CA Osasuna | --- | 2 - 4 points |
| 31/08/25 20:30 | 31/08/25 20:30 | Rayo Vallecano | FC Barcelona | --- | 2 - 4 points |