| Date | Home | Away | Result |
|---|---|---|---|
| 30/08/24 16:00 | Ruse, Elena Gabriela | Badosa, Paula | 1-2 |
| 30/08/24 16:00 | Zheng, Qinwen | Niemeier, Jule | 2-0 |
| 30/08/24 17:00 | Svitolina, Elina | Gauff, Cori | 1-2 |
| 30/08/24 17:30 | Azarenka, Viktoria | Wang, Yafan | 1-2 |
| 30/08/24 17:30 | Navarro, Emma | Kostyuk, Marta | 2-1 |
| 30/08/24 17:30 | Vekić, Donna | Stearns, Peyton | 2-0 |
| 31/08/24 00:00 | Keys, Madison | Mertens, Elise | 1-2 |
| 31/08/24 02:00 | Alexandrova, Ekaterina | Sabalenka, Aryna | 1-2 |
| 31/08/24 16:00 | Putintseva, Yulia | Paolini, Jasmine | 0-2 |
| 31/08/24 16:00 | Muchová, Karolína | Potapova, Anastasia | 2-0 |
| 31/08/24 17:00 | Bouzas Maneiro, Jessica | Pegula, Jessica | 0-2 |
| 31/08/24 17:30 | Errani, Sara | Shnaider, Diāna | 0-2 |
| 31/08/24 19:30 | Krüger, Ashlyn | Samsonova, Liudmila | 0-2 |
| 31/08/24 19:30 | Ponchet, Jessika | Wozniacki, Caroline | 0-2 |
| 01/09/24 00:00 | Świątek, Iga | Pavlyuchenkova, Anastasia | 2-0 |
| 01/09/24 02:00 | Haddad Maia, Beatriz | Kalinskaya, Anna | 2-0 |